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Using bis(pinacolato)diboron (B 2 Pin 2 ) under catalytic [Ir(COD)OMe] 2 and 4,4′-di-tert-butyl-2,2′-dipyridyl (dtbpy) as the ligand in absolute heptane at 80 °C for ≥17 h, C12-boronate ester 1 was obtained as the single isomer (Fig

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[DOI] [PubMed] [Google Scholar] [87].Schnabel R, Lackner KJ, Rupprecht HJ, Espinola-Klein C, Torzewski M, Lubos E, Bickel C, Cambien F, Tiret L, Munzel T, Blankenberg S, Glutathione peroxidase-1 and homocysteine for cardiovascular risk prediction: results from the AtheroGene study