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When the ternary complex glutathione-Fe(II)-carnosine ( 7 ) (Scheme 2) is included in the speciation study, the ternary complex is predicted to dominate over the pH range 8–10 and the concentration ratio of Complexes 3 and 7 is approximately 1:1 at pH 7.0 (Figure 6C)

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Interestingly, the same pathway may also be utilized during inflammatory responses, mediated by the tumor necrosis factor-alpha (TNF-α)

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